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High Voltage, High Frequency
Experiment, 2008 Summary
This experimental work ended in early 2008 before
testing was completed though I could restart it if funding
became available. This experiment involved high voltage
electrolysis (330 Volts chopped DC) using a small thin tungsten
wire cathode in a Potassium Hydroxide / Water solution (KOH).
The anode was 5 feet of platinum wire and 5 feet of gold wire
wound up in a coil. Calibration was done with resistors.
"Power Out" measurements were based on thermocouples on the
exterior of the vessel along with calibration curves. "Power In"
measurements are based on completely discharging a lithium ion
battery and knowing (beforehand) the energy stored in the
battery. The input power was typically in the 100 watt
range.
Vessel
The vessel consists of a 15 inch tall, 4.5 inch Diameter PVC
pipe wrapped with multiple turns of .040 inch diameter aluminum
wire. It was filled with distilled water and Potassium
Hhydroxide. The purpose of the Aluminum wire wrapped around the
exterior of the PVC pipe is so that the device has a uniform
temperature around the circumfrence and the emissivity is
constant over the entire surface. This improves the accuracy of the thermocouple measurements since the
thermocouples are underneath the aluminum wire (between the
aluminum wire and the PVC outer diameter). This surface covered
with Aluminum wire emits heat to the room through conduction,
convection and radiation. The plastic tub that it sits in is
never filled with water. The control cell is the short
white PVC pipe in the foreground and never has power applied to
it. It is used to establish an average room temperature.
  
Calibration
The equation for conservation of energy for the entire vessel is:
Energy Stored = Energy Generated + Energy In - Energy Out
(Equation 1)
also
Energy Stored = Mass * (Specific Heat Capacity) * (Change in
Temperature) (Equation 2)
where:
Mass = mass of the vessel, KOH electrolyte and aluminum wire
(all measured as one value).
Specific Heat Capacity = specific heat capacity of the vessel,
aluminum wire and the potassium hydroxide electrolyte and is measured as
one value through data correlations.
Change in Temperature = average temperature as measured by the
12 thermocouples on the exterior of the vessel.
Determining Energy Out (and similarly Power Out):
A graph of exterior wall temperature versus "Power In" (and
similarly the "Power out" because it is at steady state) was determined
using a resistive heater inside the vessel. Power levels used were
0 watts, 21 watts and 44 watts. The resulting graph is:

Determining Specific Heat Capacity:
Setting Equation 1 equal to Equation 2 and knowing that Energy
Generated equals 0 results in the following:
Mass x (Specific Heat Capacity) x (Change in Temperature) =
Energy In - Energy Out (Equation 3)
Using a resistive heater inside the vessel and and inputting a square
wave shaped heat pulse (i.e. a constant power in for 2 hours) allows the
specific heat capacity to be determined through graphing the power input
and Equation 3 (with collected data) on the same graph and using an
iterative trial and error approach. The specific heat capacity in
Equation 3 is iteratively chosen until a graph of the power output
shows a square wave shape that mimics the square wave shape of the power
input. When the curves match (as shown in the left photo
below), the correct value has been
chosen for the specific heat capacity of the system that includes
the vessel, Aluminum wire and electrolyte. Though it should be
noted that this value of specific heat capacity is not exactly equal to
the weighted mass average of the specific heat capacities of each of the
components (electrolyte, plastic and Aluminum) but it takes it takes
into account that there is a variation in temperatures of the entire
system. Also, the specific heat capacity changes with temperature and should be measured at multiple
temperatures (or in other words, multiple power levels, each having the square heat pulse
shape) for increased accuracy. The software would then use these
values of specific heat capacity during an experiment and select the
proper one depending on the exterior wall temperature. The end
result is computer software that calculates instantaneous power output
of the whole system based on temperature measurements of the exterior
wall of the vessel.
 
Referring to photo above on the right, a calibration heat pulse of 145 watts for 2.0 hours from a
resistor was introduced into the vessel - as shown in the red line
labeled "Pin(meas)". The computer program accurately
calculated (in real time) the heat pulse as shown in the dark purple line
labeled "Pin(Wall Temp based) smth". A camera was used to photograph the computer screen
and accounts for the distorted picture.
Power Output During High Voltage Electrolysis
Power output while the system was producing a plasma inside
the vessel was determined based on the thermocouples on the
exterior of the vessel and temperature, specific heat capacity
of the system and power calibration curves created using
resistive heating. Below is graph of the power out while
the plasma was operating for 3.9 hours at an average of 65
watts. The plasma was powered on for 2 seconds
and off for 5 seconds resulting in the average power of 65
watts.
 
Power Input
Input power is 330 V square wave (chopped DC) at 40 kHz
(variable up to 100 khz), 1.5 amp and 240 watts. The power is turned
on for approximately 5 seconds and then off for approximately 5
seconds on a continuous basis resulting in an average power of
120 watts. Input energy measurements are to be based
on the energy stored in a Lithium Ion battery and feeding either
all or some portion of that stored energy into the calorimeter.
The plasma electrolysis created by the high voltage square wave
creates a large amount of high frequency ringing in the current
waveform which would be difficult to measure using a high end
digital acquisition system. As a result, the energy input
is based on calibrations of the power source - the energy stored in a
Lithium ion
battery. This eliminates errors in trying to measure high
frequency current and voltage since there are lots of ringing waveforms.
Power Supply
The power supply uses an H-Bridge to turn 24 V DC from the
Lithium Ion battery into a 48 V
alternating current square wave. A transformer boosts
the 48 V up to 330 Volts and high voltage Schottky diodes
rectify it creating a 115 Volt DC waveform after it is passed
through a capacitor. The 330 Volt square wave is added to
the 115 Volt DC wave resulting in a 330 Volt square wave
(chopped DC) which is fed to the anode. The power source
is a 24 Volt Lithium Ion battery that is calibrated so that the energy
stored in it is known. The frequency can range between
3000 and 100,000 Hz and is computer controlled.

Electrodes
Anode (on right in the photo) has approximately 5 feet of
Gold wire and 5 feet Platinum wire (both .010 inch diameter)
wound in a ring shape of about 1.8 inch diameter. Cathode (on the
left) is .040 inch diameter tungsten covered with a ceramic tube
(.100 inch OD) so that only 0.10 inch of the tip is exposed.
The white cylinder supports are solid Teflon, 2 inch diameter
and roughly 1.7" long.
 
The 2 inch diameter, 9 inch long PVC pipe shown in the photo
is used to contain the anode and cathode. It is placed
inside the 4 inch diameter, 15 inch long PVC vessel containing
the water and Potassium Hydroxide. Gases generated
are captured at the top of this 2" diameter vessel and ignited
every minute or so using a grounding electrode (not shown)
that generates a spark. This grounding electrode that
generates the ignition spark is operated manually by pulling on
a lever. Results Testing not
completed and on hold due to lack of funding and time issues. |